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Chilies derive from the nightshade pepper originating from Mexico over 6000 years ago. Chili peppers contain a substance called capsaicin which produces their characteristic pungency and a range of mild to intense spice. The more capsaicin a pepper contains, the hotter it will be. Habanero has the most amount of heat followed by jalepenos, then pimentos and finally cherry peppers. Capsaicin itself is also used as topical analgesic to relieve minor aches and pains of the muscles/joints due to its anti-inflammatory properties.